Curium(III) chloride

Curium(III) chloride is the chemical compound with the formula CmCl3.[1][2][3][4][5][6][7][8][9][10][11]

Curium(III) chloride
Identifiers
3D model (JSmol)
  • InChI=1S/3ClH.Cm/h3*1H;/q;;;+3/p-3
    Key: PTLGMSBPLOHNBD-UHFFFAOYSA-K
  • Cl[Cm](Cl)Cl
Properties
Cl3Cm
Molar mass 353 g·mol−1
Melting point 695 °C (1,283 °F; 968 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Structure

Curium(III) chloride has a 9 coordinate tricapped trigonal prismatic geometry.

Preparation

Curium(III) chloride can be prepared by the reaction of curium nitride with cadmium chloride.[12]

References

  1. Sanderson, R. T. (1960). Chemical Periodicity. Reinhold, New York, USA.
  2. Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements (2nd ed.). Butterworth, UK.
  3. Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred (1999). Advanced Inorganic Chemistry. John Wiley & Sons.
  4. Trotman-Dickenson, A. F. (1973). Comprehensive Inorganic Chemistry. Pergamon, Oxford, UK.
  5. Wyckoff, R.W.G. (1963). Crystal Structures. Interscience, John Wiley & Sons.
  6. West, Anthony R. (1999). Basic Solid State Chemistry. John Wiley & Sons.
  7. Wells, A. F. (1975). Structural Inorganic Chemistry (4th ed.). Oxford, UK.
  8. Donnay, J. D. H. (1963). Crystal data determinative tables, ACA monograph number 5. American Crystallographic Association, USA.
  9. Lide, D. R (1996). Chemical Rubber Company handbook of chemistry and physics (77th ed.). Boca Raton, Florida, USA: CRC Press.
  10. Mellor, J. W. (1922–1937). A comprehensive treatise on inorganic and theoretical chemistry. London, UK: Longmans. p. volumes 1-16.{{cite book}}: CS1 maint: date format (link)
  11. Macintyre, J. E. (1992). Dictionary of inorganic compounds. London, UK: Chapman & Hall. p. volumes 1-3.
  12. Hayashi, Hirokazu; Takano, Masahide; Otobe, Haruyoshi; Koyama, Tadafumi (July 2013). "Syntheses and thermal analyses of curium trichloride". Journal of Radioanalytical and Nuclear Chemistry. 297 (1): 139-144. doi:10.1007/s10967-012-2413-7.
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